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Redox reactions 2

Terms

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Bronsted-Lowry Acid
a proton donor
Bronsted-Lowry Base
a proton acceptor
Oxidation-reduction reaction (redox)
a reaction in which there is a net movement of electrons from one reactant to or towards another
oxidation number
the charge an atom has or would have if all unevenly shared electrons were transferred completely
on: elemental form
0
on: monatomic ion
on = ionic charge
on: sum of on in compound
equals zero
on: (1)
1
on: (2)
2
on: hydrogen
+1 when in combination with nonmetals
on: fluorine
-1 in combination with metals and boron
on: oxygen
-1 in peroxides, -2 in other compounds, except with F
on: (17)
-1 with metals, nonmetals (besides O), and halogens lower in the group
on: S8
0
on: Al2O3
Al = +3 O= -2
on: N2H4
N = -2 H = +1
on: S2(O3)2-
S = +2 O = -2
on: HP(O4) 2-
H = +1 P= +5 O = -2
on: CH3OH
C = -2 H = +1 O = -2
if x loses electrons⬦..
x is oxidized x is the reducing agent x increases its oxidation number
if y gains electrons⬦.
y is reduced y is the oxidizing agent y degreases its oxidation number
12.19 mL of 0.1038 M KMnO4 were required to oxidize 25.00 mL of FeCl2. What is the molarity of the FeCl2, given the reaction: MnO4- (aq) + 5 Fe2+ (aq) + 8H+ (aq) ---> Mn2+ (aq) + 5Fe3+ (aq) + 4H2O (l)
0.01276 M
A + B ---> C
Combination
C ---> A + B
Decomposition
A + BC ---> AC + B
displacement
metal activity series
Li, K, Ba, Ca, Na, Mg, Al, Mn, Zn, Cr, Fe, Cd, Co, Ni, Sn, Pb
reversible reaction
reaction that proceeds simultaneously in both directions
equilibrium
the forward reaction and the reverse reaction proceed at equal rates
To standardize an HCl solution, 50.00 mL of HCl is put in flask with indicator. 0.1524 M NaOH goes into buret with initial reading of 0.55 mL and an end point reading of 33.87 mL. What is the concentration of the HCl solution?
0.1016 M HCl
Oxidation
the LOSS of electrons (LEO)
Reduction
the GAIN of electrons (GER)

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